Bond-settled scanning tunneling microscopy and scanning tunneling spectroscopy delivered comprehensive structural details and evidence for open up-shell singlet floor condition. The antiferromagnetic arrangement in the spins in positively doped triaza[5]triangulene was further confirmed by density operate principle calculations. The true secret aspect of triangulenes with several graphitic nitrogen is the extra p
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Triangulenes as triaza neutral radicals are getting to be promising candidates for long term purposes for example spintronics and quantum systems. To extend the likely from the State-of-the-art supplies, it can be of significance to regulate their electronic and magnetic Homes by various graphitic nitrogen doping. Here, we synthesize triaza[five]triangulene on Au(111) by cyclodehydrogenation, and its derivatives by cleaving C−N bonds.
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